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Cake day: July 15th, 2023

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  • The issue with isopropanol peroxide formation is that exposing it to air – even when just using it, like when you’re cleaning parts – starts the process. The air in the head space of your containers is also enough to form them over time. You don’t necessarily need to see solids in the containers for it to be dangerous, since they’ll crystallize out as you concentrate the solution during distillation.

    It’s also a numbers game. It probably won’t explode the first time you do it. But there’s a chance each time. Do it enough, and you’ll have an incident.

    There are chemical reductants that can clear peroxides. For industrial scale isopropanol distillation, I’m not sure what they use. It may be that they just never distill down to the point that peroxides concentrate to a dangerous level.



  • No no no no no.

    I’m a chemist. Organic chemistry PhD, now a process chemist in the industry. I do this for a living. Do not distill isopropanol that’s been exposed to air for any meaningful length of time.

    Isopropanol slowly reacts with oxygen in the air to generate peroxides that, when you concentrate them down, EXPLODE. Source. Sorry, not an open access journal. But please take my word for it.

    Unless you have a way of confirming the peroxide levels in your isopropanol are near zero, do not concentrate it down by distillation. You’ll blow up your glassware, which will probably expose what you’re distilling to your heat source, which will generate a secondary fireball.

    PLEASE do not do this.






  • Yes. Muzzle loaders. Shoot once, then spend a few minutes loading a powder charge and a bullet down the barrel. They weren’t flintlock muskets like it was the 1700s, they were modern rifles. Just loaded through the muzzles. It gives the deer a fighting chance. You have to hit on the first shot. Did you know that people also hunt with a bow and arrow? Those have been around since the Neolithic. Sometimes not using the most advanced tech is the point.

    It’s funny that you typed all that stuff trying to explain firearms to someone who you assume knows nothing about them. I’ve shot everything from pellet guns to the aforementioned muzzle loader to a .30-06 to, yes, an AR-15. I can pick up most guns and check to see if the chamber’s clear. I can disassemble and clean and put them back together.

    I want these things to go away. Not just AR-15’s. Anything semiautomatic with a magazine that can hold more than, let’s say, six rounds. Anything beyond a revolver is over the top for personal protection, and if you think that’s not true you’re a lunatic or just want to cosplay army guy. Duh, AR-15’s are the most commonly used firearm in shootings because there’s a lot of them. How about we make there be less of them and other guns that can kill so many people so quickly?



  • Okay, then. I guess I’ll ignore the muzzle loaders my dad and all his friends used to hunt with until the AR-15 became such a symbol of the “cold dead hands” crowd that they all went ahead and got one. And then a few more.

    I think the AR-15 should be banned because I think any semiautomatic rifle and pistol with a magazine capacity of more than a few rounds should be banned. That’s enough for the “guns are easier than getting medicated for anxiety” crowd to feel like they can engage in deadly personal defense without making it easy for someone to walk into a school or church or business and just unload.